When the issue is only toxicity, they tend to extend the perimeter downwind. They should do that, I agree.
But Acrylonitrile also has the capacity to polymerize explosively when exposed to heat. Its flash point is only 30°F. I imagine they don't want folks to panic. I believe this is why they have extended the perimeter for a mile in all directions.
The recommended perimeter for a spill (rather than a fire) for this material is only 150 feet.
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